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Q.

When crystals of KCl are heated in an atmosphere of Potassium vapours the colour imparted is _______ and it is due to __________ defect

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a

Lilac, Metal excess

b

Yellow, Metal deficiency

c

Yellow, Metal excess

d

Lilac, Metal deficiency

answer is A.

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Detailed Solution

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In such cases, Cl-  ions diffuse to the surface;

To combine with these Cl-  ions the Potassium atoms of the vapour  lose electrons to form K+ and thus  form KCl. 

The electrons lost by Potassium atoms occupy anionic sites.

This crystal now has anion vacancies. 

It is a metal excess defect. 

The anionic sites occupied by  unpaired electrons are called F-centres. They impart lilac colour to the crystal.

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