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Q.

When electricity is passed through a solution of AICI3 13.5 g of Al is deposited. The number of faradays must be

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a

answer is A.

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Detailed Solution

Reaction took place at cathode was :

Al+3 + 3e-→ Al

One mole of electron is deposited by one faraday, similarly 3 mole of electron is deposited by 3F.

1 mole of Al ⇒ 27 g

So, 13.5 g ⇒ 0.5 mole
If one mole of Al requires 3 F, then the amount of F requires for 0.5 mole of Al is:

Number of Faraday=0.5 mol×3 F1 mol=1.5 F

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