Q.

When equal volumes of following solution are mixed, precipitation of AgCl ?

Ksp = 1.8 × 10-10 will occur only with

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a

10-4 M  Ag+ and  10-4 M  Cl-

b

10-5 M  Ag+ and  10-5 M  Cl-

c

10-10 M  Ag+ and  10-10 M  Cl-

d

10-6 M  Ag+ and  10-6 M  Cl-

answer is A.

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Detailed Solution

 Ionic product is greater than solubility product constant precipitation occurs

Ksp = 1.8 × 10-10

Ag+ Cl- = 10-4 × 10-4=10-8    Ksp of AgCl <  Ag+ Cl- 

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