Q.

When equimolar mixture of  Cu2S  and  CuS reacts with Ba(MnO4)2 in acidic medium the final products formed are  Cu2+,SO2,Mn2+ . If molecular weights of  Cu2S,CuS and  Ba(MnO4)2 are  M1,M2  and  M3respectively. Then  EW=Equalentweight  

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a

Cu2S  and  CuShave  same  Ew's

b

Ew of ​​CuS   is​​    M26

c

Ew of ​​Ba(MnO4)2   is​​    M35

d

Ew of ​​CuS   is​​    M18

answer is A, B.

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Detailed Solution

Cu2+1S22Cu2++S+4O2                     n+=8  M18Cu+2S2Cu2++S+4O2                       n+=6  M26B+2a(Mn+7O4)2Ba2++2Mn+2    n+=10     M310

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When equimolar mixture of  Cu2S  and  CuS reacts with Ba(MnO4)2 in acidic medium the final products formed are  Cu2+,SO2,Mn2+ . If molecular weights of  Cu2S,CuS and  Ba(MnO4)2 are  M1,M2  and  M3respectively. Then  EW=Equalent weight