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Q.

When Ethane-1,2-diamine is added progressively to an aqueous solution of Nickel (II) chloride, the sequence of colour change observed will be : 

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a

 Pale Blue  Blue Green  Violet 

b

Pale Blue  Blue  Violet  Green

c

Green  Pale Blue  Blue  Violet

d

Violet  Blue  Pale Blue  Green

answer is C.

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Detailed Solution

NiH2O6(aq)+2+en(aq)NiH2O4(en)(aq)+2+2H2O
Green
NiH2O4(en)(aq)+2+en(aq)NiH2O2(en)2(aq)+2+2H2O
 Pale Blue 
NiH2O2(en)(aq)+2+en(aq)Ni(en)3(aq )+2+2H2O
Blue / purple

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