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Q.

When ethyl alcohol C2H5OH(l) and acetic acid CH3COOH (l)) are mixed together in equimolar ratio at 27°C, 33% of each is converted into ester. Then the KC for the equilibrium,

C2H5OH(l)+CH3CHOOH(l) CH3COOC2H5(l)+H2O(l)

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a

19

b

14

c

9

d

4

answer is B.

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Detailed Solution

C2H5OH(l)+CH3COOH(l)

a×23 a×23

CH3COOC2H5(l)+H2O(l)

a3 a3

K=a3×a32a3×2a3=14

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