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Q.

When excess of ammonia is added to copper sulphate the deep blue colored complex is formed. The complex is 

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a

Square planar, Diamagnetic

b

Tetrahedral, Paramagnetic

c

Tetrahedral, Diamagnetic

d

Square planar, Paramagnetic

answer is D.

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Detailed Solution

CuNH34+2 complex is formed by dsp2 hybridisation and one electron is shifted to up orbital.

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When excess of ammonia is added to copper sulphate the deep blue colored complex is formed. The complex is