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Q.

When glucose was crystallized from a concentrated solution at 30C   &   98C. It gave α & β form of glucose respectively what are the angle of rotation [α] Dfor both forms--

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a

(+)111&()19.2

b

(+)111&(+)19.2

c

(+)19.2&()111

d

()111&()19.2

answer is A.

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Detailed Solution

Concept of mutarotation

The alpha (α) anomer of D-glucose has a specific rotation of +112 degrees in water.

The beta (β) anomer of D-glucose has a specific rotation of +19 degrees. 18.7 actually, but rounding up to 19

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