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Q.

When K6[Zn(CN)4(O2)2]  is oxidised into K2[Zn(CN)4(O2)2]  then select the correct options (consider above complexes are exist)

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a

O – O bond length decreases 

b

Total number of unpaired electrons in the coordination sphere increases 

c

Zn (II) is oxidized to Zn(IV) 

d

Magnetic moment increases 

answer is A, B, D.

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Detailed Solution

O22O2 bond length decreases  

μspin=0  for  Zn+2

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