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Q.

When KMnO4 is added to oxalic acid, the decolourisation is slow in the begining but becomes instantaneous after sometime because

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a

Reaction is exothermic

b

Mn2+ acts as autocatalyst

c

CO2 is formed as the product

d

MnO4catalyses the reaction

answer is A.

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Detailed Solution

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2MnO4-+5C2O4-2+16H+2Mn+2+10CO2+8H2O
Here, KMnO4 is a reactant in the reaction which forms Mn2+ which acts as an auto-catalyst. The reaction is slow initially because MnO4​− is getting converted to Mn2+ but once Mn2+ forms, the reaction becomes faster due to the catalytic action.

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