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Q.

When mercuric iodide is added to an aqueous solution of potassium iodide, the 

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a

freezing point is lowered 

b

freezing point is elevated

c

freezing point does not change 

d

effect on freezing point cannot be predicted 

answer is B.

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Detailed Solution

In a reaction with KIHgI forms K2HgI4. This causes the amount of ions to decline, which lowers the van't Hoff factor.
ΔTf=i×kf×m
As ′ i ′ falls, the freezing point experiences less depression, which causes the freezing point to rise.

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