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Q.

When mercuric iodide is added to the aqueous solution of potassium iodide

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a

Freezing point is raised

b

Freezing point is lowered

c

Freezing point does not change

d

Boiling point does not change

answer is A.

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Detailed Solution

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HgI reacts with KI, to form K2HgI4. This causes the amount of ions to decline, which lowers the Van't Hoff factor.
ΔTf=i×kf×m

Because 'i' has gotten smaller, the freezing point is less depressed, which causes it to rise.

Therefore, option A) Freezing point is raised is the necessary answer.

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