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Q.

When MgO reacts with H2O at 25° C and 1 atm, the volume change is 4.6mLmol1

MgO(s)+H2O(l)Mg(OH)2(s)

What is the value of ΔHΔE for this reaction?

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a

4.7×101Jmol1

b

4.7×102Jmol1

c

4.7×102Jmol1

d

4.7×101Jmol1

answer is A.

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Detailed Solution

The difference between the change in enthalpy and change in internal energy is given as, 

ΔHΔE=Δ(PV)=4.6×103×1×101.3=4.7×101

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