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Q.

When mixture of CuCO3Cu(OH)2(s) and PbNO32(s) is added in dil. HCl solution:

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a

suspension of CuCO3Cu(OH)2(s) in colourless solution is precipitated

b

NO2 gas is evolved

c

coloured solution and white ppt. is produced

d

CO2 gas is evolved

answer is B, C.

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Detailed Solution

When mixture of CuCO3Cu(OH)2(s) is added in dil. HCl solution colored solution and white ppt. is produced and CO2 gas is evolved. Carbon dioxide is released when copper carbonate is treated with diluted hydrochloric acid. The following reaction will obtain

CuCO3+HClCuCl2+H2O+CO2

Sulfur dioxide gas is generated when sodium thiosulfate is treated with diluted hydrochloric acid. The reaction is having follows,

Na2S2O3+2HCl2NaCl+SO2+H2O+S

Hence, options B and C are correct.

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