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Q.

When MnO2 is fused with KOH in the presence of KNO3 as an oxidizing agent, it gives a dark green compound (A). Compound (A) disproportionates in acidic solution to give purple compound (B). An alkaline solution of compound (B) oxidises KI to compound (C) whereas an acidified solution of compound (B) oxidises KI to (D). Identify (A), (B), (C), and (D).

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Detailed Solution

Question Image

A is K2MnO4/MnO42.
B is KMnO4/MnO4
C is KIO3.
D is I2.

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