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Q.

When NaNO3  is heated in a closed vessel, oxygen is liberated and NaNO2  is left behind. At equilibrium

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a

Addition of NaNO2  favours reverse reaction

b

Addition of NaNO3  favours forward reaction

c

Increasing temperature favours forward reaction

d

Increasing pressure favours reverse reaction.

answer is C, D.

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Detailed Solution

2NaNO3(s)2NaNO2(s)+O2(g)

Appling law of Chemical Equilibrium. K=[O2(g)].   Hence addition of NaNO2  or NaNO3  will not disturb the equilibrium i.e.(a)  and (b) are wrong. Only (c) and (d) are correct.

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