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Q.

When one mole of sulphuric acid react with one mole of zinc dust in a bomb calorimeter, then U and work done correspond to

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a

ΔU>0,w=0

b

ΔU=0,w<0

c

ΔU<0,w>0

d

ΔU<0,w=0

answer is A.

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Detailed Solution

Bomb calorimeter is commonly used to find the heat of combustion of organic substances which consists of a sealed combustion chamber, called a bomb. If a process is run in a sealed container then no expansion or compression is allowed, So w=0 and ΔU=qΔU<0,w=0

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