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Q.

When only a little quantity of HgCl2(s) is added to excess KI (aq) to obtain a clear soltion, which of the following is true for this solution? (no volume change on mixing) 

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a

Its vapour pressure become lower 

b

Its boiling point is lowered 

c

Its boiling point is raised 

d

Its boiling and freezing points remain same 

answer is B.

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Detailed Solution

Due to this addition a complex [HgI4]2 will get formed as follows 

Hg2++4I[HgI4]2

or Hg2++2Cl+4I[HgI4]2+2Cl

on adding we can see that 4I ions are consumed but resultant number of particles are three. 

Hence boiling point gets decreased. 

freezing point gets increased. 

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