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Q.

When only a little quantity of HgCl2(s) is added to excess KI(aq) to obtain a clear solution, which of the following is true for this solution? (no volume change on mixing)

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a

Its boiling point is lowered

b

Its boiling and freezing points remains same

c

Its boiling point is raised

d

Its vapour pressure is lowered

answer is B.

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Detailed Solution

4KIb+HgCl2aK2HgI4+2KCl

b4a        -          a              2a [2b8a+ 3a   +   4a]=2ba 

When volume is not changed on mixing,  the boiling point of it is lowered for this case.

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When only a little quantity of HgCl2(s) is added to excess KI(aq) to obtain a clear solution, which of the following is true for this solution? (no volume change on mixing)