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Q.

When pure water is saturated with CaCO3 and 8 x 10-5 MCaC2O4 , the concentration of calcium ion in the solution under equilibrium is 8 x 10- 5 M. If the ratio of the solubility product of CaCO3 to that of CaC2O4 is 3, what is the solubility of CaCO3 in pure water?

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a

9.60×109

b

4.80×108

c

9.62×108

d

6.93×105

answer is D.

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Detailed Solution

Let solubility of CaCO3 be s1 and CaC2O4 be s2

Ksp1=s1s1+s2; Ksp2=s2s1+s2

s1s2=3 and s1+s2=8×105 s2=2×105, s1=6×105 Ksp1=48×1010

Solubility in pure water

 =48×105M=6.93×105

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