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Q.

When salt solution ' A ' is treated with dilute HCl it gives off gas ' B ', which when passed through a filter paper, moistened with potassium iodate and starch solution, gives deep blue coloration. ' A ' and ' B ' respectively are :

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a

A=Na2SO3 and B=SO2

b

A=Na2SO3 and B=CO2

c

A=Na2S and B=H2S

d

A=NaHSO3 and B=SO2

answer is A, C, D.

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Detailed Solution

(a) Na2SO3sodium sulphide(aq)+2HCl(di hydrochloric acid aq) 2NaClsodium chloride (aq)+H2O(l)water +SO2(sulphur dioxideg)

Therefore, the reaction between dil. HCl and Sodium sulfite (Na2SO3) produces Sulphur dioxide gas(SO2), Sodium chloride(NaCl) and water.

(c) Na2S(aq)+2HCl(aq)2NaCl(aq)+H2S(g)

(d)NaHSO3sodium bisulphite+HCldil.NaClsodium chloride +H2Owater +SO2sulphur dioxide

Hence, the correct option is a, c, d.

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