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Q.

When solid CuSO4 dissolves in water to make a 1 M solution, the temperature of the system increases. When solid NH4NO3 dissolves in water to make a 1 M solution, the temperature of the system decreases. Which statement(s) must be correct for these dissolving processes?

(P) ΔH values for both processes have the same sign.

(Q) ΔG values for both processes have the same sign.

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a

P only

b

Both P and Q

c

Q only

d

Neither P nor Q

answer is D.

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Detailed Solution

Two process are given here;

(i) When solid CuSO4 dissolves in water to make a 1 M solution, the temperature of the system increases. 

(ii) When solid NH4NO3 dissolves in water to make a 1 M solution, the temperature of the system decreases. 

For both the process change in enthalpy and Gibbs free energy has different sign.

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