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Q.

When solid NaF is treated with cone. H2SO4 in a test tube, followed by warming, then dimeric form of a gas is evolved, by which the test tube acquires a greasy appearance on its walls. Subsequently, the gas liberated when brought in contact with moistened glass rod forms a deposit which contains :

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a

SiO2H2O

b

H2SiO3

c

SiF4

d

H2SiF6

answer is B, C, D.

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Detailed Solution

When solid NaF is treated with cone. H2SO4 in a test tube, followed by warming, then dimeric form of a gas is evolved, by which the test tube acquires a greasy appearance on its walls. Subsequently, the gas liberated when brought in contact with moistened glass rod forms a deposit which contains 

H2SiF6SiO2H2O and H2SiO3.

Hence, options B, C and D are correct.

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