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Q.

When taken in an Eudiometer tube operating at room temperature and pressure and subjected to complete reaction, in which of the following options, the contraction in volume is greater than or equal to 30% of original volume.  [Note: Produced H2O is in liquid state] 

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a

CO(g) and O2(g) taken in a molar ratio of  2:1.

b

10mL of CH4(g) and 30mL of O2(g)

c

N2(g) and H2(g) taken in a molar ratio of  3:1.

d

N2 and H2 taken in a molar ratio of  1:3

answer is A, B, D.

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Detailed Solution

(a)2CO   +   O2          2CO2  2x            x  O             O                  2x
(b)CH4      +   2O2        CO2    +    2H2O(l)10ml     30ml   O             10ml              10ml           20ml
(c)N2             +           3H2                 2NH33x                             x                                  0(3xx3)                0                               23x
(d)N2             +           3H2                 2NH3x                               3x0                                0                             2x

 

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