Q.

When taken in an eudiometer tube operating at room temperature and pressure and subjected to complete reaction, in which of the following options the contraction in volume is greater than or equal to 30% of original volume

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a

10 ml of CH4 g and 30 ml of O2 g

b

CO(g)andO2(g) Taken in molar ratio 2:1

c

CH4g and O2g taken in a molar ratio 1: 6

d

N2g and H2(g) taken in a molar ratio 3:1

answer is A, B.

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Detailed Solution

 A)CO(g)+12O2(g)CO2(g)
 2                         1
 0                           0                              2
 %changeinmole=13×100
 B)CH4(g)+2O2(g)CO2(g)+2H2O(1)
                     10ml                                       30ml
Volume contraction =20ml 
% change in volume =2040×100  
C) N2(g)+3H2(g)2NH3(g)  
3mol                                   1mol 
[314]molL.R            2/3mol 
%change=234×100 
D)CH4(g)+2O2(g)CO2(g)+2H2O(1) 
       1mol                        6mol 
          L.R                         4mol                       1mol   
%changeinmol=27×100 

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