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Q.

When the molar concentrations of SO2, O2 and SO3 at equilibrium at certain temperature are 0.5, 0.25 & 0.25M respectively, Kc for 2SO32SO2+O2 is

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a

1mol - lit-1 
 

b

1lit2 - mol-1
 

c

0.5lit mol-1 
 

d

0.25mol2 - lit-2 

answer is C.

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Detailed Solution

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Kc=(SO2)2(O2)(SO3)=(0.5)2(0.25)(0.25)2=1 mole-lit-1.

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When the molar concentrations of SO2, O2 and SO3 at equilibrium at certain temperature are 0.5, 0.25 & 0.25M respectively, Kc for 2SO3⇌2SO2+O2 is