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Q.

When the permanganate ion, MnO4-, acts as an oxidizing agent it forms different products depending on the pH of the solution. Which species correspond to the conditions listed?

 AcidicBasicNeutral
AMn2+Mn(OH)2MnO2
BMn2+MnO42-MnO2
CMnO2MnO42-Mn(OH)2
DMn2+Mn(OH)2MnO42-

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a

A

b

B

c

C

d

D

answer is B.

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Detailed Solution

Since tendency to accept electron increases Mn2+ is acidic in nature.

Since the permanganate (VII) ion is a strong oxidizing agent it is basic in nature.

Manganese has a +7-oxidation state, which indicates a high oxidation state and an acidic oxide. Manganese's oxidation state in  MnO|  is +2, which denotes a low oxidation state and basic oxide status.

Hence, option B is correct.

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