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When toluene is treated with ${Cl}_{2}$ at high temperature without the use of any catalyst, the product obtain is

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o-chlorotoluene

m-chlorotoluene

a mixture of orhto- and para-chlorotoluenes

benzylchloride

answer is D.

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Detailed Solution

$C_{6} H_{6} {CH}_{2} Cl$ is obtained When toluene is treated with ${Cl}_{2}$ at high temperature without the use of any catalyst.

At high temperature, substitution at methyl group takes place.

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