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Q.

When XO2 is fused with an alkali metal hydroxide in presence of an oxidizing agent such as KNO3, a dark green product is formed which disproportionates in acidic solution to afford a dark purple solution. X is

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a

Mn

b

V

c

Ti

d

Cr

answer is D.

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Detailed Solution

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MnO2+2KOH+KNO3K2MnO4 (Green) +KNO2+H2OMnO42+4H+2MnO4 (Purple) +MnO2+2H2O

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