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Q.

When 10 mL of an aqueous solution of KMnO4 was titrated in acidic medium, equal volume of 0.1M of an aqueous solution of ferrous sulphate was required for complete discharge of colour. The strength of KMnO4 in grams per litre is ____ -10-2. (Nearest integer)

[Atomic mass of K=39,Mn=55,O=16 ]

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answer is 3.16.

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Detailed Solution

Let molarity of KMnO4=x

KMn+7O4+Fe+2SO4Fe+32SO43+Mn2+

(Equivalents of KMnO4 reacted )=( Equivalents of FeSO4 reacted)

No. of equivalents=VM(n-factor)

(5×x×10ml)=1×0.1×10ml x=0.02M

Molar mass of KMnO4=158gm/mol

Strength=(x×158)=3.16 g/

Hence the correct answer is 3.16.

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When 10 mL of an aqueous solution of KMnO4 was titrated in acidic medium, equal volume of 0.1M of an aqueous solution of ferrous sulphate was required for complete discharge of colour. The strength of KMnO4 in grams per litre is ____ -10-2. (Nearest integer)[Atomic mass of K=39,Mn=55,O=16 ]