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Where Nu = Nucleophile
Find out the correct statement from the options given below for the above 2 reactions.

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Reaction (I) and (II) both are of 1st order

Reaction (I) is of 2nd order and reaction (II) is of 1st order

Reaction (I) and (II) both are of 2nd order

Reaction (I) is of 1^st order and reaction (II) is of 2^nd order

answer is A.

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Detailed Solution

$\to Me O_{\cdot \cdot}^{\cdot \cdot} (+ R)$ stabilizes benzyl carbocation which leads to ${SN}^{1}$ (1st order)
$\to$ Electron withdrawing group $(- {NO}_{2})$ facilitates ${SN}^{2}$ (2^nd order)

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