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Q.

Which is correct in the case of [Fe(CN)6]4  complex

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a

Diamagnetic

b

Octahedral

c

d2sp3  hybridization

d

All are correct

answer is D.

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Detailed Solution

In [Fe(CN)6]4, Fe is in +2 oxidation state and due to the presence of strong ligand, CN  all 3d-electrons are paired and complex becomes diamagnetic. It is a low spin complex, therefore its hybridization is d2sp3 and have octahedral geometry. 

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Which is correct in the case of [Fe(CN)6]4−  complex