Which among the following forms minimum boiling azeotropes?
(i) Heptane + Octane
(ii) Water + Nitric acid
(iii) Ethanol + Water
(iv) Acetone + Carbon dioxide

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(i), (ii), (iv)

(i), (ii) only

(iv) only

(i), (iii), (iv)

answer is C.

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Detailed Solution

(c) Those azeotropes which boils at a temperature lower than boiling point of each component forms the minimum boiling azeotrope.
e.g. Heptane + octane, ethanol + water, acetone + carbon dioxide

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