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Q.

Which among the following is likely to show geometrical isomerism ?

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a

CH₂ = CH - CH = CCl₂

b

CH₃C(Cl) = C(CH)₃

c

CH₃CH = CH₂

d

CH₃CH=NOH

answer is D.

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Detailed Solution

Isomers are those molecules which having the same molecular formula but different arrangement of atoms in space. There are three types of isomerism: 1) Stereoisomerism. 2) Constitutional Isomerism. 3) Geometrical Isomerism.
Geometric isomerism exists only in those compounds that have rotational isomerism. So all geometric isomers are also rotational isomers but not vice versa. The conditions essential for satisfying geometrical isomerism is given by ${CH}_{3} CH = NOH$ (Oxime).

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Which among the following is likely to show geometrical isomerism ?