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Q.

Which amongst the following is incorrect statement?

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a

H2+ ion has one electron.

b

The bond orders of O2+,O2,O2and O22 are 2.5, 2, 1.5 and 1, respectively.

c

C2 molecule has four electrons in its two degenerate π molecular orbitals

d

O2+ion is diamagnetic

answer is C.

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Detailed Solution

(1) C2=σ1s2σ1s2σ2s2σ2s2π2px2=π2py2
      C2 molecule has 4 electrons in its two degenerate π molecular orbitals.
(2) H2+=σ1s1 H2+ion has 1 electron.
(3) O2+σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2=π2py2π2px1=π2py0
       O2+is a paramagnetic
(4) O2+=σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2=π2py2π2px1=π2py0
Bond order=1052=52=2.5
O2=σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2=π2py2π2px1=π2py0
Bond order =1062=42=2
O22=σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2=π2py2π2px2=π2py2
Bond order  =1072=32=1.5
O22=σ1s2σ1s2σ2s2σ2s2σ2pz2π2px2=π2py2π2px2=π2py2
Bond order =1082=1


 

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