Which carbonate is most unstable and requires ${\mathrm{CO}}_2$  atmosphere to be stored?

Beryllium carbonate is kept in the atmosphere of carbon dioxide as it is unstable and decomposes to give beryllium oxide and carbon dioxide.

${\mathrm{BeCO}}_3\rightleftharpoons \mathrm{BeO}+{\mathrm{CO}}_2$
When they are stored in the atmosphere of ${\mathrm{CO}}_2$ , the concentration of ${\mathrm{CO}}_2$ increases on the right side, making the reaction to shift towards the backside so that the decomposition of beryllium carbonate is prevented.

Hence, the correct option is A.