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Q.

Which compound(s) out of the following is/are not aromatic?
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a

B

b

C and D

c

B, C and D

d

A and C

answer is B.

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Detailed Solution

  •  Aromatic compounds are planar structure, cyclic, complete conjugated system (electron delocalisation) and follows Huckel rule (4n+2) n=0,1,2,3... 
  • In compounds if there is odd no. of pi bonds then it is aromatic.
  •  Anti-aromatic compounds have planar structure, cyclic, conjugation, does not follow huckel rule. It follows (4n) rule.
  •  Cyclopropenyl cation follow (4n+2) rule: aromatic. 
  • Cyclopentadienyl cation follow(4n) rule: anti-aromatic. 
  • Cycloheptatrienyl anion follow (4n) rule: antiaromatic 
  • Cycloheptatrienyl do not follow huckel rule : non-aromatic. 

Hence, the correct option is: (B) B,C and D.

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