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Q.

Which concept best explains that o-nitrophenol is more volatile than p-nitrophenol

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a

Steric hindrence

b

Hyperconjugation

c

Hydrogen bonding

d

Resonance

answer is C.

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Detailed Solution

o-Nitrophenol has intramolecular hydrogen bonding but p-Nitrophenol has intermolecular hydrogen bonding so boiling point of p-Nitrophenol is more than o-Nitrophenol.

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