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Which has the least bond angle ?

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${NH}_{3}$

${BeF}_{2}$

$H_{2} O$

${CH}_{4}$

answer is C.

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Detailed Solution

Due to lp - lp repulsions, bond angle in $H_{2} O$ is lower $(104^{0} . 5') than that in {NH}_{3} (107^{0}) and {CH}_{4} (109^{0} 28') . {BeF}_{2}$ on the other hand, has sp-hybridization and hence has a bond angle of $180^{0} .$

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