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Q.

Which is/are correct graph for given reactions?

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a

First order kinetics (A®B) 

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b

Zero order kinetics (A®B)

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c

Radioactive decay (A®B)

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d

2nd order kinetics (A®B)

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answer is A.

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Detailed Solution

Zero order reaction reaction:

A=A-kt

Comparing with equation of a straight line, y = mx + c, plot [A] against t, a straight line with slope = –k and intercept equal to [A]0.

First order reaction reaction:

ln A=ln A-kt

Comparing with equation of a straight line, y = mx + c, plot ln [A] against t, a straight line with slope = –k and intercept equal to ln [A]0.

Half life of first order reactions can be written as follows.

t1/2=0.693k

This equation for the half life implies that the half life is independent temperature

Half life of second order reactions can be written as follows.

t1/2=1k[R]0

This equation for the half life implies that the half life is inversely proportional to the concentration of the reactants.

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