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Q.

Which is/are correct statement(s) about the solubility of AgCl(s)? Given Ksp(AgCl)=10-10;KfAgNH32+=108

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a

Solubility of AgCl in 2MNH3 is 0.166 M.

b

Solubility of AgCl in 2M KBr is 10-5 mol/litre.

c

Solubility of AgCl in 2M AgNO3 is 5 x 10-11M.

d

Solubility of AgCl in pure water is 10-5 gm/litre.

answer is B, C, D.

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Detailed Solution

b) S = 10-5 mol lit-1
c) AgCl(s)⇌⇌ AgS+2           S+Cl−10−10=(S+2)S⇒s=10−102=5×10−11d) AgCl⁡(s)⇌AgNH322+Cl−

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