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Q.

Which is not true about borax?

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a

It is a useful primary standard for titrating against acids

b

One mole of borax contains 4 B -O -B bonds

c

Aqueous solution of borax can be used as buffer

d

It is made up of two triangular BO3 units and two tetrahedral BO4 units

answer is B.

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Detailed Solution

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In borax Na2B4O710H2O, among 10 water molecules 2 molecules are part of structure, ie., exists Na2B4O5(OH)48H2O

Question Image

Na2B4O5(OH)48H2O+2HCl2NaCl+4H3BO3+5H2O
Methyl orange (pH =3.7) is used to detect end point. Aq. solution of borax acts as buffer, as borax is salt of strong base NaOH and weak acid H3BO3.

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