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Q.

 Which is not true about borax?

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a

 Aqueous solution of borax can be used as buffer

b

 It is made up of two triangular BO3, units and two tetrahedral BO4 units

c

 It is a useful primary standard for titrating against acids

d

 One mole of borax contains 5 B -O -B bonds

answer is B.

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Detailed Solution

 In borax Na2 B4O7·10H2Oamong 10 water molecules 2 molecules are part of structure, i.e., exists Na2 B4O5(OH)4·8H2O

Question Image

Na2 B4O5(OH)4·8H2O+2HCl2NaCl+4H3BO3+5H2O
Methyl orange (pH = 3.7) is used to detect end point. Aq. solution of borax acts as buffer, as borax is salt
of strong base NaOH and weak acid H3BO3

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