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Q.

Which is not true about metal carbonyls? 

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a

Here CO acts as a Lewis base as well as Lewis acid
 

b

Here metal acts as Lewis base as well as Lewis acid 
 

c

Here dπ-pπ back bonding takes place
 

d

Here pπ-pπ back bonding takes place

answer is D.

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Detailed Solution

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CO is called π-acid ligand. In metal carbonyl complexes, there is donation of an electron pair from carbon to the empty orbital of metal and then simultaneously a back π-bonding is formed by sideways overlap of a filled orbital on the metal with empty antibonding π*2py orbital of CO.

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