Q.

Which is not true for a second order reaction?

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a

It can have rate constant 1×103L mol1g1

b

Its half-life is inversely proportional to its initial concentration

c

T50=1K× initial conc 

d

Time to complete 75% reaction is twice of half-life

answer is C.

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Detailed Solution

Rate constant unit for the second order reaction mol1L s1

t1/2αa1n 

Here, n=2

t1/2αa1 

This is Inversely Proportional to Half Life.

t1/2=1ak

Here, initial concentration is a.

So, time to complete 75% reaction is twice for the 1st Order Reaction not for half life.

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