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Q.

Which is the correct order of solubility in water?

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a

RbClO4>KClO4>NaClO4>LiClO4

b

CsF>CsCl>CsBr>CsI

c

LiF>LiCl>LiBr>LiI

d

LiF>NaF>KF>RbF

answer is A.

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Detailed Solution

The correct order of solubility in water  CsF>CsCl>CsBr>CsI

As the difference in the size of cation and monoanion decreases, solubility decreases. In other words, if H.E. decreases more than L. E. decreases then, solubility decreases.
L.F. is much less soluble in water because of high lattice enthalpy

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Which is the correct order of solubility in water?