Q.

Which is the correct sequence in the following properties? For the correct order mark (T) and for the incorrect order mark (F): 

(a) bond angle order : NH3 <PH3<AsH3<SbH3

(b) Melting point : NH3>SbH3>AsH3>PH3

(c) Boiling point : NH3>SbH3>AsH3>PH3

(d) Bond dipole order : NH3>SbH3>AsH3>PH3

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a

 TFTF 

b

 FFTF 

c

 FFTT 

d

 FTFT 

answer is A.

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Detailed Solution

a) F bond angle decreases down the group. 

(b) (T) M.Pt. of NH, is higher due to H-bonding.

© (F) M.Pt. and B.Pt increases from PH3 to SbH3 due to increase in molecular mass, but NH3 is exception (due to H-bonding) B.Pt. order : 

 SbH3>NH3>AsH3>PH3

(d)  (T)

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Which is the correct sequence in the following properties? For the correct order mark (T) and for the incorrect order mark (F): (a) bond angle order : NH3 <PH3<AsH3<SbH3(b) Melting point : NH3>SbH3>AsH3>PH3(c) Boiling point : NH3>SbH3>AsH3>PH3(d) Bond dipole order : NH3>SbH3>AsH3>PH3