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Which is the most stable carbocation?

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${(C D_{3})}_{3} \overset{+}{C}$

${(C H_{3})}_{3} \overset{+}{C}$

$C H_{3} \overset{+}{C} H_{2}$

$\overset{+}{C} H_{3}$

answer is B.

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Detailed Solution

Electron releasing methyl groups (+ I effect) decreases the positive charge on carbon and increases the stability.

${({CH}_{3})}_{3} C^{+} > {({CH}_{3})}_{2} CH + > {CH}_{3} {CH}_{2}^{+}$

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