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Q.

Which method is used to separate the mixture of chloroform and aniline? (Boiling point of chloroform is 334 K and the boiling point of aniline is 457 K)

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a

Evaporation

b

Crystallization

c

Fractional distillation

d

Distillation

answer is C.

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Detailed Solution

  • Since chloroform and aniline are mixtures of miscible liquids, evaporation, and crystallization cannot be used. Both Evaporation and Crystallisation are used to separate the solid-liquid mixtures. 
  • The difference in the boiling point of both liquids is more than 25K so fractional distillation is not used. 
  • So in order to separate the mixture of chloroform and aniline the best method is distillation.
  • Chloroform will vaporize first and then condense to form the liquid again in the flask. Aniline will remain in the distillation flask.
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