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Q.

Which of following is not correct with respect to bond length of the species?

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a

C2 > C22–

b

B2+ > B2

c

Li2+ > Li2

d

O2 > O2

answer is D.

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Detailed Solution

speciesC2C2-2
Electrons1214
B.O2.03.0
B.LC2  > C2-2

 

SpeciesB2+B2
Electrons910
B.O0.51.0
B.LB2+ >B2

 

SpeciesLi2+Li2
Electrons56
B.O0.51.0
B.LLi2+>Li2

 

SpeciesO2O2-
Electrons1617
B.O2.0<1.5
B.LO2>O2-

 

Electrons12345678
B.O0.510.500.510.50
Mag.propPDPDPDPD

 

Electrons891011121314151617181920
B.O00.51.01.52.02.532.52.01.51.00.50
Mag.propDPPPDPDPPPDPP

Note : Molecules (or) ions with 2,4,6,8 and 12,14,18 electrons are diamagentic remaining are paramagnetic.
 

large B.Lpropto frac{1}{B.O}
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